QM of a free particle in 1D
A particle in free space
where
where
Proof
The TISE reads
or equivalently
which has solutions
which we split into left- (
) and right-moving ( ) waves. Since there are no boundary conditions on and , there is no quantization of . Furthermore these states are non-normalizable
Properties
- The velocity of a stationary state
, whereas the group velocity matches the classical velocity.2 - The probability flux for
is .
Proof of 2.
See also
Footnotes
-
But Dirac orthonormal ↩
-
2018. Introduction to quantum mechanics, §2.4, pp. 58–59. ↩