Thermodynamics MOC

Second Law of Thermodynamics

The second law states that an Isolated thermodynamic system will never undergo a decrease in entropy.

It is important to note that a non-isolated system can decrease in entropy, but this will always result in a larger increase in entropy elsewhere. Equality occurs only for a reversible process.

Kelvin-Planck version

It can be shown that the second law is equivalent to the statement

It is impossible to construct a Heat engine operating in cycles that extracts heat from a reservoir and delivers an equal amount of work

or, equivalently

See also Thermal efficiency of a heat engine.

This is because a heat engine converts random energy of particle motion into ordered motion associated with mechanical work, a process analogous to unscrambling an egg.1


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Footnotes

  1. 2020. Essential university physics, p. 346